
Gendy Ayodya Alfarizi
Department of Environmental Engineering, Faculty of Engineering, University of Jember, Kalimantan Street 37, 68121 Jember, East Java, Indonesia
Noven Pramitasari
Department of Environmental Engineering, Faculty of Engineering, University of Jember, Kalimantan Street 37, 68121 Jember, East Java, Indonesia
Ririn Endah Badriani
Department of Environmental Engineering, Faculty of Engineering, University of Jember, Kalimantan Street 37, 68121 Jember, East Java, Indonesia
Keywords: adsorbent, detergent, efficiency, phosphate level
Abstract
Laundry activities significantly contribute to water pollution due to the high phosphate content in detergents. When released into the environment, phosphates can cause eutrophication in aquatic ecosystems. This study evaluates the potential of teak wood dust (Tectona grandis) as a low-cost and sustainable precursor for producing activated carbon to reduce phosphate levels in laundry wastewater. Activated carbon was prepared through chemical activation with H₃PO₄, which enhances porosity, surface area, and form oxygen-containing functional groups that promote phosphate adsorption. The produced activated carbon was characterized by determining its moisture content, ash content, and Fourier Transform Infrared (FTIR) spectrum to identify functional groups. The adsorption was performed in batch mode with variations in adsorbent mass (1, 3, and 5 g) and contact time (90-180 min). The objectives were to assess the effectiveness of teak wood dust-based activated carbon, determine the optimal conditions, and analyze adsorption kinetics. Results showed that teak wood dust-derived activated carbon effectively reduced phosphate concentrations below the standard limit. The highest adsorption efficiency occurred with 5 g of adsorbent and a 90-min contact time, while longer times decreased efficiency. The adsorption followed a zero-order kinetic model (R² = 0.965), indicating a nearly constant rate. These findings demonstrate that teak wood dust-based activated carbon provides an efficient, eco-friendly, and sustainable solution for treating phosphate-rich laundry wastewater.
References
Haryanto A, Hidayat W, Hasanudin U, Iryani DA, Kim S, Lee S, Yoo J. Valorization of Indonesian wood wastes through pyrolysis: A review. Energies. 2021;14(5):1407.
Islam TU, Abbas E. Validity of ANOVA under non-normality & heterogeneity. Res Square. 2022;10:21203.
Putri DP, Wahida SA, Marlinda. Utilization of epok anana peel (Musa Paradisiaca L.) as an adsorbent to reduce COD (Chemical Oxygen Demand) levels in laundry wastewater. J Inform Sains Teknol. 2022;5:71-77.
York E, Tadio J, Antwin SO. Simulating studies on phosphate (PO₄³⁻) removal from laundry wastewater using biochar: Dudinin approach. Univ J Green Chem. 2024;2(1):134-136.
Barambu NU, Peter D, Yusoff MHM, Bilad MR, Shamsuddin N, Marbelia L, Nordin NAH, Jaafar J. Detergent and water recovery from laundry wastewater using tilted panel membrane filtration system. Membranes. 2020;10(10):1-9.
Pramitasari N, Ramadani FB, Azis RA, Bezariani CS, Berliana RI, Badriani RE, Kartini AM, Fildzah CA. Activation of sugarcane bagasse biosorbent with potassium hydroxide and hydrogen chloride to reduce color of batik wastewater. J Chem Eng Environ. 2024;19(2):191–199.
Ibrahim A, Ismail A, Juahir H, Ihsan YN, Sudianto S, Ovinis M, Kassim AM, Hanapi NHM, Hafizi AD. Preparation and characterization of activated carbon obtained from Melaleuca cajuputi leaves. Carbon Trends. 2023;13:100341.
Kunusa WR, Iyabu H, Abdullah R. FTIR, SEM and XRD analysis of activated carbon from sago wastes using acid modification. J Phys Conf Ser. 2021;1968(1):012034.
Yusop MFM, Aziz A, Ahmad MA. Conversion of teak wood waste into microwave-irradiated activated carbon for cationic methylene blue dye removal: Optimization and batch studies. Arab J Chem. 2022; 15(9):103649.
Herlambang MJ, Ramandani AA, Cendekia D, Alvita LR, Wulandari YR, Shintawati S, Purnani MS, Efendi DAMN. Optimization and characterization of adsorbent from palm kernel shell waste using H₃PO₄ activator. CHEESA Chem Eng Res Artic. 2023;6(2):118-120.
Eso R, Luvi, Ririn. Effect of variation in concentration of activator H₃PO₄ on surface morphology and functional groups of candlenut shell activated Carbon. Gravit. 2021;20(1):19–23.
Tiwow VA, Rampe MJ, Rampe HL, Apita A. Infrared pattern of coconut shell charcoal purified using acid. Chem Progr. 2021;14(2):116-119.
Dittmann D, Saal L, Zietzschmann F, Mai M, Altmann K, Sabbagh DA, Schumann P, Ruhl AS, Jekel M, Braun U. Characterization of activated carbons for water treatment using TGA-FTIR for analysis of oxygen-containing functional groups. Appl Water Sci. 2022;12(8):1-13.
Fauzia E A, Purnama H. The effect of particle size on the characterization of activated Carbon from tropical black bamboo (Gigantochloa atroviolacea). J Phys Sci Res. 2021;22(2):99–106.
Bumajdad A, Hasila P. Surface modification of date palm activated carbonaceous materials for heavy metal removal and CO₂ adsorption. Arab J Chem. 2023;16(1):103450.
Yasdi, Ussarvi D, Rinald, Anggraini FJ, Cahyani SE. Coconut shell-based activated carbon preparation and its adsorption efficacy in reducing BOD from The real wastewater from kitchen restaurant (RWKR): Characteristics, sorption capacity, and isotherm model. J Presipitasi Komun Pengemb Tek Lingkung. 2021;18(1):116–130.
Wahyuhadi ME, Kusumadewi RA, Hadisoebroto R. Effect of contact time on the adsorption process of activated Carbon from banana peel in reducing heavy metal Cd and dyes using a stirring tub (Pilot Scale). IOP Conf Ser Earth Environ Sci. 2023;1203(1):012034.
Sutapa JPG, Lukmandaru G, Sunarta S, Pujiarti R, Irawati D, Arisandi R, Dwiyanna R, Priyambodo RD. Utilization of sapwood waste of fast-growing teak in activated carbon production and its adsorption properties. J Korean Wood Sci Technol. 2024;52(2):118–133.
Pungut P, Al Kholif M, Pratiwi WDI. Reduction of chemical Oxygen demand (COD) and phosphate levels in laundry waste using the adsorption method. J Sains Teknol Lingkung. 2021;13(2:155-165.
Ozcan DO, Hendekci̇ MC, Ovez B. Enhancing the adsorption capacity of organic and inorganic pollutants onto impregnated olive stone derived activated Carbon. Heliyon. 2024;10(12):e27890.
Joubory TGH, Hyali EAS, Hadeethi MR. Study of the factors affecting the adsorption efficiency of some chemical pesticides activated carbon at the nanoscale. Int J Adv Chem Res. 2023;5(1):89–98.
Hutami AT, Warsito EA. The effect of fermentation time and mass variation of Saccharomyces cerevisiae on the characteristics of virgin coconut oil from the fermentation process of coconut milk. J Edu Health. 2023;14(4):801–805.
Islam MS, Ahmed A, Rahman MM, Hasan MN. Production of activated carbon from sawdust for phosphate removal from wastewater. J Water Process Eng. 2023;56:104074.
Revellame ED, Fortela DL, Sharp W, Hernandez R, Zappi ME. Adsorption kinetic modeling using pseudo-first order and pseudo-second order rate laws: A review. Clean Eng Technol. 2020;1:100032.
Maslukah L, Zainuri M, Wirasatriya A, Widiaratih R. Study of adsorption and desorption kinetics of phosphate ions (PO₄³⁻) in sediments of Semarang and Jepara waters. J Ilmu Teknol Kelaut Trop. 2020; 12(2):385–396.
Hou L, Liang Q, Wang F. Mechanisms that control the adsorption–desorption behavior of phosphate on magnetite nanoparticles: The role of particle size and surface chemistry characteristics. RSC Adv. 2020;10(4):2378–2388,.
Zhang L, Liu Z, Cui GL, Chen L. Biomass-derived materials for electrochemical energy storages. Prog Polym Sci. 2015;43:136-164.
Faisal M, Suhartana S, Pardoyo P. Modified natural zeolite Fe metal as phosphate adsorbent (PO₄³⁻) in wastewater. J Sci Appl Chem. 2015;18(3):91–95.
Coates J. Interpretation of infrared spectra, a practical approach. In R. A. Meyers (Ed.), Encyclopedia of Analytical Chemistry. Chichester John Wiley Sons Ltd. 2019;10:10815-10837.
Bakti AI, Gareso PL. Characterization of active carbon prepared from coconut shells using FTIR, XRD, and SEM techniques. Biruni Sci J Phys Educ. 2024;7(1):33–39.
National Standardization Agency. SNI 06-3730-1995: Specification for activated carbon from coconut shell. Jakarta: BSN. 1995.
National Standardization Agency. SNI 06-6989.31-2005: Water and wastewater – Part 31: Method of Test for Phosphate (PO₄³⁻) Content by Spectrophotometry. Jakarta: BSN. 2005.

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